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  5. Synthesis and structures of novel octadecanuclear clusters [Cu<sub>12</sub>RE<sub>

Synthesis and structures of novel octadecanuclear clusters [Cu<sub>12</sub>RE<sub>

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：aorong
【摘 要】
：
The novel octadecanudear Cu-RE cluster haw been isolated from the reaction system of aqueous Cu2+-RE3+-pyb (RE=Sm, Eu; pyb=pyridine betaine) and characterized b
【作 者】
：
陈小明 吴玉銮 王如骥 
【机 构】
：
DepartmentofChemistry,ZhongshanUniversity,Guangzhou510275,China,TsinghuaUniversity,Beijing100084,Chi
【出 处】
：
中国科学：化学英文版
【发表日期】
：
1996年5期
【关键词】
：
HETEROMETALLIC cluster copper(II) rare-earth(III). 
【基金项目】
：
Project supported by Guangdong Natural Science Foundation and Zhongshan University
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The novel octadecanudear Cu-RE cluster haw been isolated from the reaction system of aqueous Cu2+-RE3+-pyb (RE=Sm, Eu; pyb=pyridine betaine) and characterized by single-crystal structural analysis. The results show that the clusters comprise a [Cu12RE6(μ3
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