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本文合成五种含硫 Schiff 碱配合物:cr~Ⅱ(Same-H)_2(OEt)_2Cl,Cr~Ⅱ(Dmabtsc-H)(Dmabmc)Cl,cr~Ⅱ(Vilit-H_2)_2Cl_3,Mn~Ⅱ(Sat-H_2)_2(Satsc-H)Cl及Mn~Ⅱ(Vilitsc-H_2)_2(Vilitsc-H)_2,进行了元素分析和IR表征,试验了吸、放O_2和CO的性能,结果表明,配合物与吸气量的摩尔比接近2:1。
In this paper, five kinds of sulfur-containing Schiff base complexes were synthesized: Cr ~ Ⅱ (OEt) _2Cl, Cr ~ Ⅱ (Dmabtsc-H) Elemental analysis and IR characterization were carried out to investigate the properties of O_2 and CO on Sat_H_2 _2 (Satsc-H) Cl and Vilitsc-H_2 _2 (Vilitsc-H_2) It shows that the molar ratio of complex to inhalation is close to 2: 1.