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研究了在不同共溶剂存在下的酸性水溶液介质中,酞菁铁(Fde)催化氢醌(HQ)氧化的活性;考察了不同来源的FePc的活性差异所产生的原因;初步研究了FePc催化氢酿氧化的反应机理.结果表明:FePc的催化活性和FePc的表面结构及共溶剂有关;活性较高的FePc样品其结晶度较低.
The catalytic activity of iron phthalocyanine (Fde) for the oxidation of hydroquinone (HQ) in acidic aqueous media with different co-solvents was investigated. The reasons for the differences in the activity of FePc from different sources were investigated. The effects of FePc on catalytic hydrogen The results showed that the catalytic activity of FePc was related to the surface structure of FePc and the co-solvent. The FePc with higher activity had lower crystallinity.