L625 Raman lidar has been developed for water vapor measurements over Hefei, China since September 2000. By transmitting laser beam of frequency-tripled Nd:YAG laser, Raman scattering signals of water vapor and nitrogen molecules are simultaneously detected by the cooled photomultipliers with photon counting mode. Water vapor mixing ratios measured by Raman lidar show the good agreements with radiosonde observations, which indicates this Raman lidar is reliable. Many observation cases show that aerosol optical parameters have the good correlation with water vapor distribution in the lower troposphere.