Ga(ClO4)3-catalyzed reaction of 1,2-aryldiamines and a-bromoketones to afford 2-substituted quinoxalines in good yields is described.The reaction proceeded via grinding process with 10％(molar fraction) catalyst under solvent-free conditions at room temperature.For unsymmetrical o-phenylenediamines bearing electron-withdrawing groups,regio-selective quinoxalines were obtained.