【摘 要】
：
A novel approach to the synthesis of 4-phenylethynylphthalic anhydride has been described. The target compound was synthesized by Pd/Cu catalyzed Sonogashira co
【机 构】
：
College of Chemistry
【基金项目】
：
the National Undergraduates’ Innovative Experiment Project of China and the Undergraduates’ Innovative Experiment Project of Sichuan University for financial support
论文部分内容阅读
A novel approach to the synthesis of 4-phenylethynylphthalic anhydride has been described. The target compound was synthesized by Pd/Cu catalyzed Sonogashira coupling reaction between phenylacetylene and 4-bromophthalic acid which was for the first time employed as start material, followed by dehydration of 4-phenylethynylphthalic acid. Compared with traditional synthetic routes, this method provides several advantages such as readily available raw materials, convenient manipulation and high yield. The products were characterized by IR, 1H NMR, 13C NMR, MS and elemental analysis, respectively.
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