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The title compound[Co(2,2-bipy) 3] 4[Mo 10V 6O 40(PO 4)] 2·4H 2O was synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is double tetracapped Pseudo-Keggin cluster anions. The crystal is triclinic, space group P-1 with a={1^316 5(3)} nm, b=1^438 2(3) nm, c=2^764 4(6) nm, α=79^51°, β=89^95°, γ=68^89°, V={4^789 3(17)} nm 3, Z=1, D c=2^176 g/cm 3, R=0^075 5, wR=0^205 3, S=0^995.
The title compound [Co (2,2-bipy) 3] 4 [Mo 10V 6O 40 (PO 4)] 2 · 4H 2O was synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is double tetracapped Pseudo-Keggin cluster anions. The crystal is triclinic, space group P-1 with a = {1 ^ 316 5 (3) } nm, b = 1 ^ 438 2 nm, c = 2 ^ 7644 (6) nm, α = 79 ^ 51 °, β = 89 ^ 95 °, γ = 68 ^ 89 °, V = {4 ^ 789 3 (17) } nm 3, Z = 1, D c = 2 ^ 176 g / cm 3, R = 0 ^ 075 5, wR = 0 ^ 205 3, S = 0 ^ 995.