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本文以作者在温控水/有机两相及温控非水液/液两相催化领域的研究工作为主线,对这一领域的研究进展做一评述,重点是环绕经典水/有机两相催化体系存在“应用范围受底物水溶性限制”的根本问题展开。特别是对“温控相转移催化”做了较为详细的介绍,同时,按体系介质不同,对氟两相体系、PEG两相体系、离子液体两相体系等非水液/液两相体系以及温控相分离催化分别做了阐述。
In this paper, the author’s work in the field of temperature controlled water / organic two-phase and temperature-controlled non-aqueous liquid / liquid two-phase catalysis is the main line, and the research progress in this field is reviewed. The emphasis is on the classical two- System exists “the scope of application by the substrate water solubility restrictions ” the fundamental problem started. In particular, the “temperature-controlled phase-transfer catalyst” made a more detailed introduction, at the same time, according to the different media, fluorine two-phase system, PEG two-phase system, ionic liquid two-phase system and other non-aqueous liquid / System and temperature control phase separation catalyst were elaborated.