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A new coordination polymer containing mixed ligands,namely[Ni(S2COiBu)2(DBPMF)·(CHCl3)]∞(DBPMF = 2,7-dibromo-9,9-(4-pyridylmethyl)fluorine),has been synthesized and structurally characterized by elemental analysis and single-crystal X-ray diffractions.X-ray structural analysis reveals that each Ni atom is coordinated by two isobutyl xanthogenate molecules and two nitrogen atoms from two DBPMF ligands to form octahedral coordination geometry.DBPMF acts as a bridge to form a coordination polymer.Fluorescence property of this coordination polymer displays a broad emission band at λ = 413 nm.Thermal analysis shows that the solvent molecule CHCl3 can be stabilized in the crystal structure until 140℃.