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[期刊论文] 作者:Kaichuan Yan,Hua He,Jianglian Li,Yi Luo,Ruizhi Lai,Li Guo,Yong Wu,
来源:中国化学快报(英文版) 年份:2021
Carbene transfer reactions play an important role in the field of organic synthesis because of their abil-ity to construct a variety of molecules. Herein, we reported on blue light-induced cyclopropenizations of N-tosylhydrazones in water, ......
Synthesis of 2-aminothiazoles via rhodium-catalyzed carbenoid insertion/annulation of sulfoxonium yl
[期刊论文] 作者:Yuncan Chen,Shan Lv,Ruizhi Lai,Yingying Xu,Xin Huang,Jianglian Li,Guanghui Lv,Yong Wu,
来源:中国化学快报(英文版) 年份:2021
Sulfoxonium ylides as carbene precursors couple smoothly with thioureas in the presence of 5 mol% of rhodium(Ⅱ) acetate dimmer via carbenoid insertion to afford the corresponding 2-aminothiazoles with high chemoselectivity,providing a facil......
[期刊论文] 作者:Xin Huang,Yingying Xu,Jianglian Li,Ruizhi Lai,Yi Luo,Qiantao Wang,Zhongzhen Yang,Yong Wu,
来源:中国化学快报(英文版) 年份:2021
A new strategy is developed for the synthesis of 1-aminoisoquinoline derivatives.This Rh(Ⅲ)-catalyzed[4 + 2]annulation reaction employs benzamidines as efficient directing groups and the vinylene carbon-ate as an acetylene surrogate.Additi......
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