单晶X-射线衍射相关论文
Nonlinear optical material of a low-dimensional coordination polymer:Synthesis,structure,NLO and flu
采用是的不对称的 2-mercapto-5-methyl-1,3,4-thiadiazole 和 2,2-bipyridine 混合了 ligands,新低维的协作聚合物[Zn (MMTA ) 2 (......
The inverted triplesalen ligand H 6 feld Me has been synthesized from 2,4,6-triformyl-phloroglucinol and a ketimine sale......
We studied the reactivity of an osmium vinyl complex containing a coordinated hydroxyl group OsCl2(PPh3)2[CH=C(PPh3)CHPh......
Three new cobalt complexes,{[Co5(tci)2(bimb)3(3-O)2(H2O)2]·3DMF·4H2O}n(1),{[Co3(tci)2(bib)]·2DMF·2H2......
以L-脯氨酸和氯乙酰氯为原料合成维格列汀的重要中间体(S)-1-(2-氯乙酰基)吡咯烷-2-甲酸(1).甲醇体系室温挥发14 d培养得到1的无色......
作为[FeCl_2(H_2O)_4]Cl·(C_(36)H_(36)N_(24)0_(12))·4H_2O加合物的一部分,反式[FeCl_2(H_2O)_4]~+的结构首次被单晶X 射线衍射......
合成了瓜环与氯化锶及间苯二酚形成的化合物,其结构为单晶X-射线分析方法所确定。晶体属于正交晶系,空间群为P2(1)2(1)2,其中a=15.......
本文合成了化合物[(C36H36N24O12)ErNa(NO3)Cl(H2O)4]·(NO3)2·5H2O,利用X射线衍射法测定了单晶结构。晶体属正交晶系,空间群为Pn......
本文合成了化合物[(C36H36N24O12)ErNa(NO3)Cl(H2O)4]·(NO3)2·5H2O,利用X射线衍射法测定了单晶结构.晶体属正交晶系,空间群为Pna......
在金属配合物中,如果金属离子处于不饱和配位时,可以作为电子接受体而与作为电子给予体的含N配体形成配合物.配合物及其反应有着广......
本论文主要研究了稀土金属桥联膦宾配合物的合成、结构及反应性能。主要包括以下几个方面的内容:
1.首个含p3-配体的可溶性稀......
该论文共分为两个部分:第一部分为铂金属高硼烷簇合物的晶体结构研究,第二部分为大环络合物(冠醚络合物)的晶体结构研究.该论文的第一......
作者研究合成了六种新的双核钴配合物与一种新的双核锌配合物,并用元素分析,摩尔电导、紫外可见光谱(UV-vis),红外光谱(IR),循环伏安法......
本论文基于单手性的(1R,2R)-环己二胺设计了7个含双吡啶基手性配体,利用单手性配体构筑了14个具有单核、双核、一维、二维或三维结构......
研究了二苯并18-冠-6、KSCN与ZnC12在1,2-二氯乙烷中的反应,得到标题配合物:[K(18-C-6)(CH3CN)]2[zn(NCS)4].通过元素分析、红外光......
合成了瓜环与氯化锶及间苯二酚形成的化合物,其结构为单晶X-射线分析方法所确定.晶体属于正交晶系,空间群为P2(1)2(1)2,其中α=15.......
合成了瓜环与氯化锶及间苯二酚形成的化合物,其结构为单晶X-射线分析方法所确定。晶体属于正交晶系,空间群为P2(1)2(1)2,其中a=15.658(3......
蓬莪术环二烯是从温莪术油中分离得到的一个倍半萜类化合物,其化学名称为(5E,9E)-3,6,10-三甲基环癸烷并[b]呋喃-5,9-二烯,通过1H NM......
One Novel 2D Co(Ⅱ) Polymer with 1,2,3-Triazole Derivative: Crystal Structure, Fluorescence and Hirsh
One new polymer [Co(L)(H2O)2]n(1) was synthesized by 4-(ethoxycarbonyl)-5-methyl-1H-1,2,3-triazole-1-carboxylic acid(Emtc) under t......
Synthesis, Crystal Structure and Antitumor Activity of N-[5-(Benzylthio)-1,3,4-thiadiazol-2-yl]-4-ch
The title compound N-[5-(benzylthio)-1,3,4-thiadiazol-2-yl]-4-chlorobenzamide(C_(16)H_(12)ClN_3OS_2, M_r = 361.86) was d......
从中药菖蒲中分到一个新化合物——菖蒲新倍半萜醇。用单晶X-射线衍射法确定了其结构。...
杂环化合物1-苯基-3-甲基-4-吡唑啉-5-酮(HPMP)为β-二酮,不仅可用作金属离子的萃取剂,还可用于核磁共振的位移试剂,也可用于激光......
有不同 Fe 的四 Fe-Mg 电气石的结构的数据从 Xinjiang,四川,和云南省满足的单个水晶的 X 光检查衍射,中国,在房间温度和 100 渠 ? 被......
Thiocyanate-controlled Copper(Ⅱ)-L-arginine Complex:Synthesis,Crystal Structure and Characterization
A novel thiocyanate-controlled copper(Ⅱ)-L-arginine complex with the formula of Cu(Arg)(SCN)_2(1,Arg:L-arginine) has be......
lisiguangite 的水晶结构, CuPtBiS3 从 Yanshan 山, Chengde 府, Hebei 省,中国被单个水晶 X 光检查衍射决定了。它与 = 属于斜方晶的......
Synthesis, Structure and Magnetic Property of a New Three-dimensional Copper(Ⅱ) Coordination Polymer
A new 3D copper(Ⅱ) coordination polymer, {[Cu_2(tbip)_2(1,3,5-tib)]×2H_2O}n(1, H_2 tbip = 5-tert-butyl isophthalic......
Two novel Zn(Ⅱ)-organic frameworks[(CH3)2NH2][Zn(BPT)]·0.5DMF(1)and[Zn2(HBPT)2(1,4-bis)](2)(H3BPT=biphenyl-3,4,5-t......
A Double Helix Coordination Polymer Generated from 2-((Pyridin-4-ylmethyl)thio)-5-(quinoline-2-yl)-1
The new ligand 2-((pyridin-4-ylmethyl)thio)-5-(quinoline-2-yl)-1,3,4-oxadiazole(L) and Ag Cl O4 produced a new coordinat......
A new Zn(Ⅱ) complex,[ZnL_2Br_2](L = triadimenol) was synthesized by the reaction of ZnBr_2 with the commercial fungicid......
Synthesis, Crystal Structure and Photoluminescence Property of Potassium Terbium Polyphosphate KTb(P
The potassium terbium polyphosphate crystal KTb(PO_3)_4 has been synthesized using a high temperature solution reaction ......
研究了二苯并18-冠-6、KSCN与ZnCl2在1,2-二氯乙烷中的反应,得到标题配合物:[K(18-C-6)(CH3CN)]2[Zn(NCS)4]。通过元素分析、红外光谱、单晶......
A new coordination polymer {[Ba(L)(H2O)5]·H2O}n(1, H2 L = 3,3'-((((ethane-1,2-diylbis(oxy))-bis(2,1-phenylene))......
Synthesis and Molecular Structure of 5-Amino-7-(benzo[d][1,3]dioxol-5-yl)-2,3-dihydro-1H-indene-4,6-
The title compound, C18H13N3O2, has been synthesized for the first time by the multicomponent reaction of cyclopentanone......
Heterometallic Trinuclear Ni2Zn and Ni2Mn Complexes of Macrocyclic Oxamide: Synthesis and Crystal St
Two novel heterometallic trinuclear complexes of macrocyclic oxamide [Mn(NiL)2(HBTC)H2O] (1) and [Zn(NiL)2(HBTC)H2O] (2)......
Syntheses, Crystal Structures, and Biological Activities of Two Enantiomeric 2-Trifluoromethylthieno
Two enantiomeric 2-trifluoromethyl-6,7-dihydro-5H-cyclopenta[4,5]thieno[2,3-d]pyrimidin-4-amine derivatives were synthes......
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A new borophosphate compound Cd3 BPO7(Mr = 490.98) has been successfully synthesized by conventional high temperature so......
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Two Fluorescent Complexes Assembled by Schiff Base 2-Methoxy-6-(phenyliminiomethyl) Phenolate Ligand
Two d10 metal complexes Zn(NCS)2(C14H13NO2)2 (1) and [Cd(NO3)2(C14H13NO2)2]·4H2O (2) assembled by 2-methoxy-6-(phen......
Hydrothermal Synthesis, Structural Characterization and Proton-conducting Property of a 3-D Framewor
A novel Zr-substituted polyoxometalate(POM) H2K3[Na6(H2O)9][Zr3Na3O3(H2O)3-(GeW9O34)2]·12H2O(1) has been made under hydroth......
Synthesis and Crystal Structure of a New Cadmium(Ⅱ) Coordination Polymer with Ethylenediaminetetraac
A new cadmium(Ⅱ) coordination polymer,namely,[KCd2(edta)I]n(1,H4edta = ethylenediaminetetraacetic acid),has been prepar......
A single crystal of Li3Ba2Ho3(WO4)8 was obtained from a flux of Li2WO4 under an air atmosphere. The structure of the pur......
Syntheses and Crystal Structure of a New Molecular Clip Based on Diethoxycarbonyl Glycoluril: C54H38
A new glycoluril derivative 2 has been synthesized and characterized by singlecrystal X-ray diffraction. It crystallizes......
Dinuclear Copper(Ⅱ) Complex with a New Polycarboxylate Ligand:Syntheses,Characterization and Crystal
A dinuclear copper(Ⅱ) complex,[Cu2(HL)2(H2O)6] 1(H3L = 2,4,6-tri(3-carboxy-phenylthio)-1,3,5-triazine),was synthesized ......
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Syntheses, Crystal Structures and Photoluminescence Properties of Cadmium(Ⅱ) and Nickel(Ⅱ) Complexes
Two novel complexes, [Cd2(BMQU)2Cl4] (1) and [Ni(BMQU)2HPO4]·1.5H2O (2) (BMQU = 2-(2-benzimidazolyl)quinoline), wer......
Synthesis, Characterization and X-ray Crystal Structure of 2-Benzyl-7-butoxyl-9-isobutyl-1-methyl-β-
2-Benzyl-7-butoxyl-9-isobutyl-1-methyl-β-carboline bromide(H-2-65) was synthesized by the reaction of Harmine with 1-io......