Research on the mineral composition and microstructure changes of iron ore sinter during the gas-sol

来源 :第五届宝钢学术年会 | 被引量 : 0次 | 上传用户:safafaffaf
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  Characteristics of the gas-solid reduction reaction between iron ore sinter and CO gas at 1 273 K were studied with Thermal-Gravity analyzer.The samples used in current study are industrial iron ore sinter produced in Shougang sintering plant.The Thermal-Gravity analyzer was produced in CAHN Corporation from German,the balance accuracy and max temperature of which was 1.0 pdg and 1 735C respectively.The study mainly focused on the mineral composition,microstructure changes and porosity changes during various stages of the reduction.The micro-structure,mineral compositions and porosity of sample before reduction,300-/o reduced sample,700-/o reduced sample and fully reduced sample were investigated.It was found that the reduction rate decreased with higher reduction degree due to the mineral composition changes during the reduction.The hematite and calcium ferrite in the sinter was firstly reduced during the reduction due to its good reducibility.The reduction rate of hematite is higher than that of calcium ferrite.At the reduction degree of 300-/o,the original mineral phases and structures remained in the core area of the sample.The reduction reaction of hematite-ymagnetite and calcium ferritemagnetite occurred in the outer layer.The hematite and calcium ferrite was reduced t0 44.4% and 60.40-/. respectively.At the reduction degree of 700-/o,all the hematite,calcium ferrite and magnetite in the outer layer were reduced to metal iron,only 360-/o wustite was left in the core area.Some original structures such as columnar structure and mixed structure can be observed in some area of 700-/o reduced sample.Most of the area in the reduced sample appeared to be even metal iron layer due to the nucleation and growth of the metal iron;lt can be found that loose structures and cracks were generated during the reduction from calcium ferrite to magnetite.The reduction reaction began with the loose structures and spread to the nearby area.In the area of micro-pores,the reducing gas can easily diffuse to the reaction interface to proceed the reduction reaction effectively.So increasing the content of micro-pores is an effective way to improve the reducibility of the sinter.According to the porosity testing results,the porosity of the sample increased from 12.43 0-10 t0 53.440-/o after reduction,and most of the increment happened in the early stage of the reduction.
其他文献
采用Thermo-Calc软件、金相显微镜、力学拉伸试验、硬度试验以及夏比冲击试验对不同Ni含量18Cr-2Mo超纯铁素体不锈钢的微观组织和力学性能进行了研究.试验结果表明,Ni含量在2%以下时,母材基体保持完全的铁素体相,且Ni含量的改变对材料微观组织基本没有影响;Ni含量每增加l%,母材的屈服强度和抗拉强度提高25 MPa左右,延伸率有一定下降;Ni含量增至2%时,材料的韧脆转变温度由原始母材
活套控制是热连轧精轧机组能否正常运转的关键,同时也是保证带钢宽度和厚度质量控制能否稳定的前提。介绍了宝钢1580 mm热轧三电自主集成改造中活套控制对象和所采用的基本模型,阐述了活套热负荷调试过程中一些注意事项。此次三电改造中,活套控制一次投入成功,并创造了开轧以来活套零废钢的记录。
钢铁企业原料厂是为炼铁、烧结、焦化、球团、自备电厂等用户提供原燃料贮存、处理和输送的主体,是钢铁企业散装料储存处理和厂内物流集散中心,也是粉尘污染和原燃料生产成本的重要环节.随着行业的快速发展,产能过剩、环境污染、资源能源消耗等问题日益突显,国家、行业和企业在环保降耗、节能减排、高效低耗等方面不断提高要求,原料场的粉尘地面污染、物料损耗、土地资源利用率、生产运行成本等问题已备受行业关注.原料的环保
CSIRO tested a Crosslands Resources ( "CRL") concentrate sample to investigate its utilisation strategies in both sintering and pelletising.The concentrate was predominantly magnetite,very high in Fe
烧结合铁原料来源较多.经验表明,在温度、湿度等天气因素和水分含量等存储条件的影响下,同一种物料的烧结制粒性能会发生改变.同时也有研究表明,物料的润湿性对其烧结制粒性能存在较大的影响.为了探索铁矿粉润湿性对制粒与烧结性能的影响,宝钢股份与重庆大学合作进行相关研究工作.首先简要介绍了含铁原料的润湿性能参数及其测试方法,然后针对一定的烧结用料结构,在测试含铁原料的润湿性能参数后,确定了烧结锅试验中需要预
研究了高精矿配比条件下,针对常规烧结法、MPS法.HPS法三种制粒方式,对制粒效果、烧结矿产质量、烧结矿的矿相和冶金性能等方面进行了对比实验的研究.结果表明:通过综合比较混合制粒后粒度组成,混合料中Ca0的含量、混合料中游离C的含量,三种方案的制粒效果比较明显,制粒效果的顺序为MPS法优于HPS法优于常规.三种制粒方式对烧结矿的产质量指标的差别不大,均能满足生产要求.但MPS法有较高的成品率、转鼓
The granulation property of iron ores was generally influenced by their wettability,surfaceroughness and shape of the iron ore.In this study,the surface roughness and shape of iron ores were character
Over the last two decades,Australian iron ore production has increased substantially and Australian products are now the major component in many Asia Pacific ore blends.Important differentiating chara
Australian limonite is widely used all over the world,known with the properties of high assimilation ability and low bonding strength.Although measures such as quasi-particle design and densification
Assimilation characteristic reflecting the beginning formation temperature of liquid phase plays important role on the formation and flow of liquid phase,and strength of sinter body in the sintering p