During the past two decades,the design and synthesis of coordination polymers have attracted considerable attention because of their interesting architectures and potential applications in areas such
Metal-organic frameworks(MOFs)are very promising self-sacrificing templates to develop the large-scale fabrication of new functional materials owing to their versatile functionalities and tunable poro
When compared with pure transition metal or lanthanide complexes,3d–4f heterometallic compounds combine the advantages of favorable magnetic coupling between the metal centres and the high magnetic an
Cyclic coordination clusters(CCCs)have received increasing attentions owing to their aesthetically fascinating structures,high symmetry and potential applications in molecular magnets,catalysis,host-g
The complex cation 1(Fe(bipy-NH2)3 2+),which was constructed from compound [Fe(H2Bpz2)2(bipy-NH2)] and bipy-NH2 ligands,effectively bind CO2 in-situ from a methanol-water solution,through the formatio
The field of lanthanide-based single-molecule magnets(SMMs)has been flourishing over the last decades due to the strong spin-orbital coupling interactions and large anisotropy of lanthanide ions[1].