Metal-Hydrogen Bridge and Agostic BondingInfrared Spectra and Theoretical Calculations

来源 :第十五届全国化学动力学会议 | 被引量 : 0次 | 上传用户：known9

【摘要】

：

Infrared spectra of matrix isolated dibridged Si(μ-H)2MH2 and tribridged Si(μ-H)3MH molecules(M = Zr and Hf,or Be and B) were observed following the laser-abl

【作者】

：

Bing Xu Jie Zhao Wenjie Yu Tengfei Huang Xuefeng Wang

【机构】

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DepartmentofChemistry,TongjiUniversity,Shanghai200092

【出处】

：

第十五届全国化学动力学会议

【发表日期】

：

2017年8期

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Infrared spectra of matrix isolated dibridged Si(μ-H)2MH2 and tribridged Si(μ-H)3MH molecules(M = Zr and Hf,or Be and B) were observed following the laser-ablated metal atom reactions with SiH4 during condensation in excess argon and neon,but methylidene complex CH2＝MH2 with agostic bonding was formed in metal atom reactions with CH4.

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