Two new porphyrin-polyoxometalate hybrids,namely,[(C4H9)4N]10H2[{COH NC(CH2O)3P2V3W15O59}2C44N4H28]·CH3CN 1 bearing two covalent-bonded Wells-Dawson type polyoxometalates(POMs)and [(C4H9)4N)]5H[COHNC(
The utilization and transformation of abundant gaseous waste,carbon dioxide as C1 source,into valuable chemical products deserves persistent attentions for the chemists due to the requirement of the g
MOFs have generated a great deal of interest in recent years for potential applications in gas storage,separation,sensor devices,biomedicine and catalysis.
Supramolecular chemistry and crystal engineering are active fields in chemistry due to the novel topologies and potential applications in host-guest chemistry,catalysis,and electrical conductivity [1,
Metal-Organic Frameworks(MOFs),promising porous materials generally constructed from rigid organic linker and metal/metal cluster,have been extremely studied as potential anode,cathode,and electrolyte