Toward Perfect Control of Perylene Diimide End Group in Polyfluorene via Suzuki Catalyst Transfer Po

来源 :第七届国际高分子化学学术研讨会 | 被引量 : 0次 | 上传用户：sogood1918

【摘要】

：

Six aryl Pd(Ⅱ) bromide complexes based on perylene diimide derivative (Ar) and phosphine mixed-ligands were successfully synthesized by directly oxidative addi

【作者】

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Huiliang Sun Yanxiang Cheng

【机构】

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ChangchunInstituteofAppliedChemistry,China;ChineseAcademyofSciences,China

【出处】

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第七届国际高分子化学学术研讨会

【发表日期】

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2016年9期

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Six aryl Pd(Ⅱ) bromide complexes based on perylene diimide derivative (Ar) and phosphine mixed-ligands were successfully synthesized by directly oxidative addition of Ar-Br to the Pd(0) precursor.These complexes with the general formulas ArPdBr(PCy3)2 (PCy3 = tricyclohexylphosphine;Pd1-Pd3) and [ArPdBr(TXP-2,4)]2 (TXP-2,4 = tri-2,4-xylylphosphine;Pd4-Pd6) are stable and can be handled in air at room temperature.

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