The novel four-coordinate manganese organic-inorganic hybrid crown ether clathrate,[H2en-(18-crown-6)2]2+[MnCl4]2-(1)(en= ethanediamine),has been prepared via hydrothermal reaction.
The lanthanide-based SMMs are attracting the growing attentions due to the intrinsic strong spin-orbital coupling and magnetic anisotropy of lanthanide(Ⅲ)ions[1].
Single-molecular magnets(SMMs)have been of great interest in the field of molecular magnetic materials since the discovery of the Mn12-Ac SMM at the beginning of the 1990s,Besides their theoretical in
It has become increasingly obvious that high magnetic anisotropy is the most critical requirement for an SMM since the reports of double-decker phthalocyanine TbⅢ SIMs1 and SIMs including 3d metal ion
Because the molecule-based magnetic materials can provide fundamental insight into interesting magnetic phenomena and are with potential application in magnetic devices,the molecular magnetism has alw