Direct synthesis of dimethyl carbonate from CO2 and methanol under low pressure

来源 :中国化学会第一届全国二氧化碳资源化利用学术会议 | 被引量 : 0次 | 上传用户:cocksun
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  CO2 is an attractive C1 building block in organic synthesis as it is naturally abundant,economical,non-toxic,and nonflammable.
其他文献
会议
聚离子液体同时具有离子液体的导电性、热稳定性和不易燃性以及聚合物的可加工性、易回收性、高机械稳定性等优异特性,在催化领域具有广泛应用前景。我们之前报道了离子液体/有机碱协同催化CO2 环加成合成环状碳酸酯[1]。
Due to the depletion of the oil reserves and environmental problems,there has been an increasing demand for thesustainable use of renewable natural resources as raw chemical materials.
基于聚离子液体具有亲核性卤素阴离子和银卡宾具有Lewis 酸性,我们制备了一系列聚离子液体负载银卡宾催化剂(Poly(Ag-NHC/IL))催化CO2 与环氧化物环加成反应。
CO2 is known as one of the sources of global warming,however it is also an abundant,renewable,non-toxic,inexpensive and environmentally C1 resource.Vegetable oil as a renewable green resource has beco
Rh/TiO2 has been regarded as a very promising catalyst for the low-temperature CO2 methanation.1 However,the atomic-level reaction mechanism that dictates the reactivity and selectivity of CO2 reducti
Recently,increasing efforts had been devoted to synthesize CO2-based polycarbonates(PCs)with various functional and chemically reactive moieties to tailor the physicochemical properties.
从二氧化碳出发,合成新型聚脲可避免传统工艺异氰酸酯、光气法中所带来的环境问题,但脲基氢键和极性作用较强,导致聚脲的溶解能力受限,进一步影响到后续聚合反应的深入研究。
Functional polycarbonates(PCs)are currently of great interest due to the significant chemical and biological performances to meet different demands.
二氧化碳是一种储量丰富、无毒可再生的C1 资源.以二氧化碳为原料合成高附加值的精细化学品的方法学研究是二氧化碳催化转化的热点.1 以二氧化碳为羧酸源合成环状酸酐的研究报道较少.