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Lead-free piezoelectric (1-x)BaTiO3-xSrZrO3(BSTZ-100x,x=0,0.025,0.05,0.075,0.10,0.15) ceramics were prepared via a conventional mixed-oxide method.The effects of SrZrO3 on the structure,piezoelectric and pyroelectric properties of BaTiO3 ceramic were investigated.