【摘 要】
：
An efficient and diastereoselective synthetic procedure for the functionalized 1,8,9,9a-tetrahydro4H-1,4-ethanoquinolizine derivatives was successfully developed via domino reactions of 4-dimethylamin
【机 构】
：
College of Chemistry & Chemical Engineering,Yangzhou University,Yangzhou 225002,China
【出 处】
：
The 24th International Society of Heterocyclic Chemistry Con
论文部分内容阅读
An efficient and diastereoselective synthetic procedure for the functionalized 1,8,9,9a-tetrahydro4H-1,4-ethanoquinolizine derivatives was successfully developed via domino reactions of 4-dimethylaminopyridine, acetylenedicarboxylates and arylidene cyanoacetates in dimethoxyethane.The similar domino reactions of 4-methoxypyridine, acetylenedicarboxylates and arylidene cyanoacetates selectively resulted in the corresponding 1,8,9,9a-tetrahydro-4H-1,4-ethanoquinolizines or buta-1,3-diene-1,2,4-tricarboxylates depending on the substrates and reaction conditions.
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