N-Methylcarbamoyl Azide:Spectroscopy,X-ray Structure and Decomposition via Methylcarbamoyl Nitrene

来源 :第十五届全国化学动力学会议 | 被引量 : 0次 | 上传用户：hhzzmm

【摘要】

：

N-Methylcarbamoyl azide Me(H)NC(O)N3 has been synthesized and structurally characterized.Both N3 and CH3 groups in the molecule adopt syn conformation with the C=O bond.Upon flash vacuum pyrolysis at

【作者】

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Huabin Wan Manabu Abe Didier Bégué Xiaoqing Zeng

【机构】

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College of Chemistry,Chemical Engineering and Materials Science,Soochow University,215123 Suzhou,P.R

【出处】

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第十五届全国化学动力学会议

【发表日期】

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2017年10期

【关键词】

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azides nitrenes matrix-isolation X-ray crystallography photochemistry

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　　N-Methylcarbamoyl azide Me(H)NC(O)N3 has been synthesized and structurally characterized.Both N3 and CH3 groups in the molecule adopt syn conformation with the C=O bond.Upon flash vacuum pyrolysis at 800 K,the azide mainly decomposes into Me(H)NNCO/N2 and MeNCO/HN3 through Curtius-rearrangement and retro-ene reaction,respectively.

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N-Methylcarbamoyl Azide:Spectroscopy,X-ray Structure and Decomposition via Methylcarbamoyl Nitrene

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