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Transition metal phosphide(TMP)was used as cocatalyst to enhance the photocatalytic activity of Cd0.5Zn0.5S solid solution for photocatalytic H2 production and nitrogen fixation under visible light irradiation.The Ni2P/Cd0.5Zn0.5S photocatalyst was characterized by X-ray diffraction patterns(XRD),transmission electron microscopy(TEM),UV-vis diffuse reflectance spectra(DRS)and X-ray photoelectron spectroscopy(XPS).