一种核磁共振手性溶剂化试剂

来源 :中国化学会第九届全国有机化学学术会议 | 被引量 : 0次 | 上传用户：zhshgu1983

【摘要】

：

由于核磁共振波谱检测具有方便、简单、快速、环境友好等优点,同时随着小型化、微型化核磁共振的发展和普及,基于NMR 方法的手性识别及ee 值的测定越来越受到化学家的青睐[1],它能够观测到手性分子中每一个功能基团在手性识别过程中的表现,能清晰地表明主客体相互作用的位点,并且可以预测非对映体络合物的空间构象.一般说来,NMR 主要借助于化学位移、耦合常数、弛豫时间、NOE、扩散系数等参数来研究手性识别

【作者】

：

李高伟曹江明宗文刘亚婷张艳胡利雷新响

【机构】

：

南京大学功能生物分子研究所医药生物技术国家重点实验室南京 210093 温州大学化学与材料工程学

【出处】

：

中国化学会第九届全国有机化学学术会议

【发表日期】

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2015年7期

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一种核磁共振手性溶剂化试剂

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