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Spinodal-hardening is one of the most important strengthening mechanisms in the Cu-Ni alloys,and is largely related to the face-centred cubic (fcc)-type miscibility gap (MG).The fcc-type MG in the Cu-Ni alloy system has been predicted to be at temperatures lower than 354.5 ℃,suggesting to use spinodal-hardening in the Cu-Ni alloys is limited below 354.5 ℃.