超临界二氧化碳中聚合诱导自组装制备含氟聚合物微球

来源 :中国化学会2017全国高分子学术论文报告会 | 被引量 : 0次 | 上传用户：magic1136

【摘要】

：

　　超临界二氧化碳(scCO2)具有化学惰性、低毒、不易燃、易回收和后处理简单等优点，是一种环境友好聚合介质。本文合成出在CO2 中有较好溶解性的含氟大分子链转移剂，并以其作

【作者】

：

霍志远马佳晨 Umair Azhar 耿兵徐安厚张书香

【机构】

：

山东省氟化学化工材料重点实验室,济南大学化学化工学院,济南250022

【出处】

：

中国化学会2017全国高分子学术论文报告会

【发表日期】

：

2017年10期

【关键词】

：

超临界二氧化碳聚合诱导自组装 RAFT聚合嵌段共聚物

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论文部分内容阅读

　　超临界二氧化碳(scCO2)具有化学惰性、低毒、不易燃、易回收和后处理简单等优点，是一种环境友好聚合介质。本文合成出在CO2 中有较好溶解性的含氟大分子链转移剂，并以其作为分散稳定剂，以scCO2 为介质进行甲基丙烯酸甲酯(MMA)单体的活性可控分散聚合，通过聚合诱导自组装制备出不同粒径大小的含氟聚合物微球。

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超临界二氧化碳中聚合诱导自组装制备含氟聚合物微球

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