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Polythiophene(PT)and its derivatives have been intensively studied for application in organic photovoltaics(OPVs).[1]Among these polymers,the regioregular poly(3-hexylthiophene)(P3HT)has been the most prominent photovoltaic donor material and played a critical role in the development of OPVs with the bulk heterojunction(BHJ)structure[2] due to its high crystallinity,thermal stability,and good hole mobility.