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Mn1-xZnxFe2O4 (0≤x≤1, step:0.2) nano powders were fabricated by a template-assisted sol-gel method.The microstructure and magnetic properties of Mn1-xZnxFe2O4 were measured by XRD and VSM.The effects of Zn on the microstructure and magnetic properties of Mn1-xZnxFe2O4 were studied.The results showed that Mn1-xZnxFe2O4 (0≤x≤1) nano powders are all spinel structure, their crystal plane spacing decreases with the increase of Zn content;the saturation magnetization and Curie temperature of samples decrease monotonically,while the coercivity of samples increases first and then decreases.