β,β-菲并-meso对叔丁基-苯基钴卟啉@MWCNTs:增强π-π相互作用用于稳健的电化学催化

来源 :The First Asian Conference on Porphyrins, Phthalocyanines an | 被引量 : 0次 | 上传用户：divide2058

【摘要】

：

合成并表征了含有菲并吡咯环的β，β-菲并-meso对叔丁基-苯基钴卟啉(Co(Ⅱ)TPTPP)，其性质使用光谱学和电化学进行了详细的分析，并且利用DFT和TD-DFT理论计算进行了验证。电化学结果表明π扩张的Co(Ⅱ)TPTPP通过非共价键的方式固定在多壁碳纳米管上，然后再将其修饰到玻碳电极的表面进行测试的。

【作者】

：

顾婷婷朱卫华梁旭

【机构】

：

江苏大学化学化工学院,江苏镇江,212013

【出处】

：

The First Asian Conference on Porphyrins, Phthalocyanines an

【发表日期】

：

2019年3期

【关键词】

：

析氢(HERs) 氧还原(ORRs) π-π相互作用

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