Polynuler lanthanide clusters have attracted great interest in the recent years due to their potential and extensive applications in a variety of areas such as luminescence,1 magnetism,2 catalysis,3 e
Ln-MOFs are a novel class of functional materials with adjustable pore size and versatile structural features.They have been applied to the detection of metal ions or organic molecules in the environm
A series of isostructural 3D lanthanide metal-organic frameworks(Ln-MOFs),[Ln(tftpa)1.5(2,2-bpy)(H2O)](Ln = Gd 1,Eu 2 and Tb 3,H2tftpa = tetrafluoroterephthalic acid)have been synthesized by hydrother
Metal–metal-bonded compounds with low-valent metal centers have attracted much attention because they often exhibit specific reactivity towards small molecules and can afford novel adducts/complexes t
Transition-metal imido species are implicated as key intermediates in important transition-metal catalyzed transformations,e.g.C-H amination,olefin aziridation,dinitrogen functionalization,and have th