【摘 要】
：
A new 1-D chain,{[Ni6(OH)3(H2O)2(en)3(PW9O34)](1,3-bdc)}[Ni(en)2]·H2O (en = ethylenediamine,1,3-bdc= Benzene-1,3-dicarboxylic acid),based on the Ni6-cluste
【机 构】
：
MOE Key Laboratory of Cluster Science,School of Chemistry,Beijing Institute of Technology,Beijing 10
【出 处】
：
2016年中西部地区无机化学化工学术研讨会
论文部分内容阅读
A new 1-D chain,{[Ni6(OH)3(H2O)2(en)3(PW9O34)](1,3-bdc)}[Ni(en)2]·H2O (en = ethylenediamine,1,3-bdc= Benzene-1,3-dicarboxylic acid),based on the Ni6-cluster substituted polyoxometalate,has been synthesized underhydrothermal conditions and its structure has been determined by single crystal X-ray diffraction.It is found that acombination of the the hexanuclear [Ni6(μ3-OH)3]9+ cluster and trivacant Keggin B-α-PW9O34 unit act as a SBU,further linked by 1,3-bdc ligand to form a 1-D chain.Crystal data:orthorhombic space group P212121,a =13.3441(3) (A),b = 14.2773(3) (A),c = 36.0138(11) (A),V = 6861.3 (A)3,R1 = 0.0473.
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