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5. Ruthenium-catalyzed trans-hydroboration of alkynes:a general mechanism for HE(E=H,B,Si,Ge,Sn)reactio

Ruthenium-catalyzed trans-hydroboration of alkynes:a general mechanism for HE(E=H,B,Si,Ge,Sn)reactio

来源 :The 15th ICQC International Congress of Quantum Chemistry(第1 | 被引量 : 0次 | 上传用户：woshishagua6

【摘 要】

：

Metal-catalyzed hydroboration of alkynes usually proceed with a cis-addition manner.Applications of trans-hydroboration via a vinylidene intermediate are limited in terminal alkynes.

【作 者】

：

Lijuan Song Lung Wa Chung Xinhao Zhang Yun-Dong Wu 

【机 构】

：

Lab of Computational Chemistry and Drug Design,Laboratory of Chemical Genomics,Peking University She

【出 处】

：

The 15th ICQC International Congress of Quantum Chemistry(第1

【发表日期】

：

2015年5期

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Metal-catalyzed hydroboration of alkynes usually proceed with a cis-addition manner.Applications of trans-hydroboration via a vinylidene intermediate are limited in terminal alkynes.

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