γ型石墨单炔/TiO2异质结的光催化制氢特性

来源 :第十六届全国太阳能光化学与光催化学术会议 | 被引量 : 0次 | 上传用户:zxwss
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利用太阳能光催化分解水制氢是具有研究意义的课题,纳米碳材料包括石墨烯,碳量子点等均用来与半导体复合提高光催化制氢活性.石墨炔类材料是sp2 杂化碳原子和sp 杂化原子共轭构成的二维平面网络结构的一类新型碳的同素异形体[1].
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光催化水分解制氢是一种经济而可持续的利用太阳能来制备洁净能源氢气的方式,因此寻找和开发高效稳定的光解水产氢光催化剂成为光催化领域的研究热点.氮化碳(g-C3N4)因其具有无毒、廉价、导带位置比较负的优点而引起人们的关注.
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在热聚合法制备类石墨相氮化碳(C3N4)的过程中,煅烧气氛的选择往往会对材料的形貌、结构和光生载流子行为产生一定的影响,最终改变C3N4 的光催化性能.
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