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Ball milling the mixture of Mg(NH2)2, LiH and NH3BH3 in a molar ratio of 1∶3∶1 results in the direct liberation of 9.6 wt% H2 (11 equiv.H), whichis superior to those binary systems such as LiH-AB (6 equiv.H), AB-Mg(NH2)2 (0equiv.H) and LiH-Mg(NH2)2 (4 equiv.H), respectively.