Directed Amination of Aryl Methyl Ethers Mediated by Ti(NMe2)4at Room Temperature

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户:Ling_cheng
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  An efficient C-O amination of aryl methyl ether has been achieved under catalyst-free conditions.This transformation proceeds via imine directed Ti(Ⅳ)-mediated cross-coupling reactions between aryl methyl ether and Ti(NR2)4(R = Me and Et)at room temperature,straightforwardly leading to a series of arylamines.
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