【摘 要】
：
An asymmetric cascade reaction of metallo-isochromenylium has been successfully established with multiple-bond formation viaan enantioselectiveoxa Diels-Alder reactionbycooperative catalysis of Pd(OAc
【机 构】
：
State Key Laboratory of Coordination Chemistry,Nanjing National Laboratory of Microstructures,School
【出 处】
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The 24th International Society of Heterocyclic Chemistry Con
论文部分内容阅读
An asymmetric cascade reaction of metallo-isochromenylium has been successfully established with multiple-bond formation viaan enantioselectiveoxa Diels-Alder reactionbycooperative catalysis of Pd(OAc)2 and (S)-Trip.[1,2] This methodology showed good to excellent overall yields and enantioselectivities (up to ＞99.5％ ee), abroad substrate scope, and high efficiency in establishing densely multiplechiral centers including quaternary carbons of variablebridged ring systems.
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