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The titania/hydroxyapatite composites (TiO2/HAp) were prepared by a hydrothermal method.The physical and chemical properties of the resulting products (TiO2,HAp and TiO2/HAp composites) were fully characterized and the photocatalytic activities of as-prepared TiO2/HAp composites were evaluated by the decontamination of nitric oxide (NO) in air with the simulated solar light irradiation.