硼基配体钌配合物催化氢化CO2反应的活性调控研究

来源 :第十三届全国量子化学会议 | 被引量 : 0次 | 上传用户:feixiang_16
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  将CO2 转化为甲酸(盐)是解决温室效应和能源危机的策略。提高催化剂活化稳定的CO2 分子的活性是目前该课题最大的困难。我们前期的工作发现氢基的对位基团可以显著影响Ru–H 键的性质,进而影响活化CO2 的活性,所以我们认为具有强的对位效应的硼基配体对于其对位氢基的活性会有显著的提高。
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