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The effect of calcium formate on water requirement of normal consistency, compressive strength, drying shrinkage and rate of mass loss of cement pastes containing fly ash were studied.The influence of calcium formate on pore structure and content of non-evaporable water of cement pastes containing fly ash were investigated through mercury intrusion porosimetry (MIP) and combustion method.The results showed that calcium formate has water reducing effect, and accelerations the early hydration of cement pastes containing fly ash and the refinement of pore structure, it can also decrease the rate of mass lose of cement pastes under drying condition.Calcium formate can improve the early compressive strength of cement pastes containing fly ash obviously and increase the drying shrinkage.However, increase of fly ash replacement can reduce the effect of calcium formate on drying shrinkage of cement pastes containing fly ash.