Porous Metal-Organic Polyhedron Constructed from Dirhodium Paddlewheels:Synthesis,Structure and Cata

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Self-assembly of dirhodium(Ⅱ) tetraacetate(Rh2(Oac)4) with a dicarboxylic acid 3,3-(1,3-phenylenebis(ethyne-2,1-diyl))dibenzoic acid(H2pbeddb) gives rise to a metal-organic polyhedron(MOP) containing Rh-Rh bonds with the formula of [Rh4(pbeddb)4(H2O)2(DMAC)2](1).
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