双膦配体原位转化合成银配合物及其光电流响应

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户:gaofeijacky1
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  多膦配体与银形成的配合物结构多变,部分具有半导体性质,在光照下可以展现出较好的催化能力。我们以一种二膦配体bdppeda(N,N'-bis(diphenylphosphanylmethyl)ethylenediamine)在甲醛存在下与AgBr反应,得到了一个少见的配合物[Ag2(L1)2(μ-Br)2](L1 = N,N'-bis(diphenylphosphanylmethyl)-tetrahydroimidazole)。
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