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Two novel Strandberg-type organophosphomolybdate hybrid compounds H2[Co(bipy)3(C6H5PO3)2Mo6O16] 1,and [(Co2(H2O))(bipy)4(C6H5PO3)2Mo5O15]·3H2O 2(bipy=2,2-bipyridyl)were prepared under mild hydrothermal conditions.