氨基醇底物上选择性碳杂偶联反应机理的理论研究

来源 :第九届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户:Biremoon
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亚铜催化的Ullmann类型碳杂偶联反应是当代有机合成中的重要方法,并在生物活性分子制备及药物化学等领域表现出巨大的应用前景.
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一般催化反应在溶液中进行,所以需要考虑其溶剂效应.目前常用的方法是采用PCM模型,该方法需要定义溶剂与溶质作用的空穴,一般采用分子中各原子的van der Waal半径的重叠来构
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