【摘 要】
：
富锂层状正极材料是一种新型的锂离子电池正极材料,因其具有理论容量高(＞200mAh/g)、低成本、充放电电压高(＞3.5V vs Li/Li+)等优点,已广泛成为人们的研究热点[1-2].Kim等[3]通过共沉淀法合成了0.3Li2MnO3·0.7LiMn1-xNiyCo0.1O2(x=0.3,y=0.2),2.0～4.6 V时放电容量为200 mAh/g；Kang等[4]采用溶胶凝胶法合成了0.
【机 构】
：
上海大学理学院化学系 上海市上大路99号,200444;江苏省新型功能材料重点实验室,江苏,常熟,215500
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富锂层状正极材料是一种新型的锂离子电池正极材料,因其具有理论容量高(＞200mAh/g)、低成本、充放电电压高(＞3.5V vs Li/Li+)等优点,已广泛成为人们的研究热点[1-2].Kim等[3]通过共沉淀法合成了0.3Li2MnO3·0.7LiMn1-xNiyCo0.1O2(x=0.3,y=0.2),2.0～4.6 V时放电容量为200 mAh/g；Kang等[4]采用溶胶凝胶法合成了0.5Li2MnO3·0.5LiNi0.44Co0.25Mn0.31O2,C/11,0.5C和1C不同倍率充放电时,放电容量分别为250,225,200 mAh·g－1.
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