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通过熔体快淬方法获得Pr(Fe1 - xCox)2 合金条带,经过X 射线衍射、差示扫描量热计和磁性测量对其结构、磁性和热稳定性进行了研究.发现当Co 的含量x 大于0-2 时才可能获得Pr(Fe ,Co)2 立方Laves 相化合物.对Pr(Fe0 .6Co0 .4)2 合金,在快淬速度为30 m/s 时,条带由Pr2(Fe,Co)17 ,Pr(Fe,Co)2 和富稀土相组成;在速度为40 m/s 时,获得了几乎单相的Pr(Fe0 .6Co0.4)2 化合物,其居里温度为305 ℃;在速度为45 m/s 时,除了Pr(Fe0 .6Co0 .4)2 化合物外,还存在少量的非晶相.Pr(Fe0.6Co0.4)2 化合物在770 ℃以上发生分解.用40 m/s 快淬纳米晶粉胶粘磁体有大的磁致伸缩系数(λ∥- λ⊥= 140 ×10 - 6) 和高的硬磁性能(iHc= 398 kA/m) .
Pr (Fe1 - xCox) 2 alloy strips were obtained by melt quenching method. The structure, magnetic properties and thermal stability of the samples were investigated by X - ray diffraction, differential scanning calorimetry and magnetic measurements. It is found that Pr (Fe, Co) 2 cubic Laves phase compounds are obtained when the content of Co is more than 0-2. For Pr (Fe0.6Co0.4) 2 alloy, the bands consist of Pr2 (Fe, Co) 17, Pr (Fe, Co) 2 and rare earth rich phase at the quenching velocity of 30 m / At 40 m / s, almost single-phase Pr (Fe0.6Co0.4) 2 was obtained with a Curie temperature of 305 ℃. At a velocity of 45 m / s, Compounds, there are still a small amount of amorphous phase. The Pr (Fe 0.6 Co 0.4) 2 compound decomposes above 770 ° C. The magnetostriction coefficient (λ∥-λ⊥ = 140 × 10 -6) and the high hard magnetic property (iHc = 398 kA / m) were obtained with 40 m / s quenched nanocrystalline powder bonded magnets.