Hydrothermal reaction of 5,5-dicyano-3,3-bipyridyl ligands and sodium azide under the Louis catalyzer of CuSO4 in the presence of water and ethanol,we obtained a novel metal organic tetrazole complexe
To synthesize coordination polymers(CPs)or metal-organic frameworks(MOFs)with specific structure is still of a great challenge,and has been hotspot of chemistry for decades not only due to the interes
Cr2Ge2Se7(en)5 crystallize in the triclinic space group P-1.The basic building blocks of Cr2Ge2Se7(en)5 are cations [Cr(en)3]3+,anions [CrGeSe4(en)2]-and anions [Ge2Se6]4-.
C-alkylpyrogallol[4]arenes(abbreviating as PgCns,where n is the length of the associated alkyl tail),which contain four pyrogallol moieties linked together by –CHR– units to form bowl-shaped molecules
Duringthe past two decades,polynuclear Ln(Ⅲ)clusters have received much more interest due to their appealing structures andtheir interesting magnetic property[1].
In order to overcome the disadvantages of Li/SOCl2 batteries,such as low voltage and small capacity,a series of phthalocyanine derivatives(MPcOc)as catalysts were added into the electrolyte.
Metal-organic frameworks(MOFs),as a class of crystalline porous materials with large surface area and tunable pore sizes,have been widely used in many areas[1],especially in the field of electrochemis
As a typical flexible polypodal ligand,1,3,5-triazine-2,4,6-triamine hexaacetic acid(H6TTHA)contains six nitrogen atoms and six carboxyl groups,which can display versatile conformations and coordinati
The chiral coordination polymers(CCPs)have received great interest,not only due to their fascinating topologicalstructures,but also fortheir potential applications in magnetic,asymmetric catalysis,ena