Octupolar Bis(porphyrinato)Terbium(Ⅲ)Complex with the Highest Off-resonant Hyperpolarizability

来源 :中国化学会第四届卟啉与酞菁学术研讨会 | 被引量 : 0次 | 上传用户:zhangjianmei88
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  Novel bis(porphyrinato)terbium double-decker complex HTb(DADAPor)2 with a twisted cuboid octupolar molecular symmetry exhibits the largest off-resonant first hyperpolarizability as evaluated by harmonic light scattering measurements with √(β2HIS)1907 = 1680 × 10-30 esu.
其他文献
  本文采用固相法合成了主体材料KCa2Ta3O10,并利用二次离子交换法制备了Ca2Ta3O10-/CoTMPyP 纳米复合材料。利用XRD、IR、UV、SEM 对复合材料进行表征。并通过循环伏安法
  光敏剂分子在特定波长光的照射下,可通过电子转移或能量传替产生活性氧等毒性物质,从而达到杀灭周围细胞或微生物等目的[1]。
  细菌耐药性是21世纪威胁人类生命健康的最重要元凶之一。面对细菌耐药性的加剧,发展新型的抗菌药物用以治疗耐药细菌已经成为了当务之急[1]。
  MTcPc/SnO2 composite are synthesized by a facile developed “In situ hydrothermal” technique with the Sn(OH)4 and MTcPc as the precursors.
会议
  Herein,the photocatalyst of graphitic carbon nitride(g-C3N4)coupled with zinc phthalocyanine(g-C3N4/ZnPc)was prepared by hydrothermal reaction immobilizing
会议
  光动力学疗法(Photodynamic therapy,PDT)是一种非侵入式治疗恶性肿瘤的方法,主要通过光敏药物在特定波长光源的激发下发生光动力学反应,产生单线态氧而发挥其破坏肿瘤细
  本文通过传统的固相法合成了KNb3O8层状铌酸盐,通过盐酸酸化之后,利用TBAOH对质子化产物进行剥离,获得了纳米片。以H2TMPyP和FeCl2为原料合成了金属卟啉FeTMPyP,利用静电
  Metallophthalocyanines have many interesting properties and applications in several important technological fields,such as conductivity,chemical catalysis,p
会议
  Organic-inorganic hybrids are highly desired for the enhancement of the photo-induced charge transfer,which is a key factor in determining the photocatalyti
会议
  Porphyrin,phthalocyanine and their analogues have been intensively studied in the past one century in the field of life science,chemistry,physics,and materi
会议