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溶质分子瞬间光激发后,由于电荷的重新分布而引起周围溶剂分子响应的过程,称为溶剂化过程.伴随溶剂化动力学过程,溶液的瞬态荧光光谱的峰位不断移动,直至达到一稳定峰位值.因此,溶剂化动力学过程可以通过时间分辨荧光谱的峰位移动进行研究.
溶剂化动力学研究中的瞬态荧光光谱矫正
【摘 要】
：
溶质分子瞬间光激发后,由于电荷的重新分布而引起周围溶剂分子响应的过程,称为溶剂化过程.伴随溶剂化动力学过程,溶液的瞬态荧光光谱的峰位不断移动,直至达到一稳定峰位值.因此,溶剂化动力学过程可以通过时间分辨荧光谱的峰位移动进行研究.
【机 构】
：
河北大学,物理科学与技术学院,河北省光电信息材料重点实验室,保定 071002;中国科学院物理研究所,软物质物理重点实验室,北京,100190
【出 处】
：
第14届全国化学动力学会议
【发表日期】
：
2015年7期
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