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5. Synthesis,structure,and tunable white-light emission of heteronuclear Zn2Ln2 arrays using a zinc com

Synthesis,structure,and tunable white-light emission of heteronuclear Zn2Ln2 arrays using a zinc com

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户：ma_mwj

【摘 要】

：

New heteronuclear Zn2Ln2 clusters [Zn2L2Ln2(hfac)6)](Ln = La(1),Eu(2)and Tb(3))have been synthesized based on a flexible Schiff base(H2L = N,N-bis(salicylidene)-3,6-dioxa-1,8-diaminooctane)and β-diket

【作 者】

：

Ting Gao Rui Jia Peng-Fei Yan 

【机 构】

：

Key Laboratory of Functional Inorganic Material Chemistry,Ministry of Education,Heilongjiang Univers

【出 处】

：

第九届全国无机化学学术会议

【发表日期】

：

2015年7期

【关键词】

：

heteronuclear Schiff base β-diketonate luminescence white-light 

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　　New heteronuclear Zn2Ln2 clusters [Zn2L2Ln2(hfac)6)](Ln = La(1),Eu(2)and Tb(3))have been synthesized based on a flexible Schiff base(H2L = N,N-bis(salicylidene)-3,6-dioxa-1,8-diaminooctane)and β-diketonate ligand(hfac = hexafluoroacetylacetonate).White-light emission was realized by codoping Eu(Ⅲ)ion in the La(Ⅲ)complex.

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