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Solvothermal reactions of Cd(OAc)2·2H2O with 1,4-bis[(pyridin-3-yl)methoxy]benzene(bpmb)and benzene-1,2-dicarboxylic acid(H2L)in MeOH/H2O at 165°C gave rise to one new Cd(Ⅱ)-based metal-organic framework [Cd2L2(bpmb)]n(1).