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We have investigated the assembling of oligothiophenes on graphene grown on polycrystalline copper foil by CVD.It was found that the oligothiophenes form similar supramolecular assembly on graphene covering different facets of copper (Cu(111), Cu(100)), and the Moiré pattern has neglectable influence on the assembling behavior of oligothiophenes, which highlights the weak interaction between graphene and copper.1